How to Measure Acid and Alkali with Conductivity Meters?
Time:2023-05-11 Read:240
Reading guide: Conductivity meters are a useful tool for measuring the acidity and alkalinity of solutions. However, it is important to calibrate the meter and use it in conjunction with other methods to obtain accurate and reliable results.

If you are looking for a way to measure the acidity or alkalinity of a solution, a conductivity meter is a great tool to use. Conductivity meters measure the electrical conductivity of a solution, which is directly related to its ionic strength and thus, the concentration of ions present in the solution. In this article, we will discuss how to measure acid and alkali with a conductivity meter.


Acidity and alkalinity are important parameters in various fields such as chemistry, biology, agriculture, and environmental science. The pH scale is used to measure the acidity or alkalinity of a solution. However, pH measurements are not always accurate, especially when dealing with complex or heterogeneous solutions. Conductivity measurements provide a more reliable and precise method to determine the acidity or alkalinity of a solution.

Understanding Conductivity

Conductivity is the measure of a solution's ability to conduct electricity. The higher the concentration of ions in a solution, the higher the conductivity. The conductivity of a solution is affected by the temperature, pressure, and concentration of ions in the solution. The SI unit of conductivity is Siemens per meter (S/m).

Calibration of Conductivity Meter

Before using a conductivity meter, it is essential to calibrate it. Calibration ensures that the meter gives accurate readings. Calibration involves adjusting the meter to a standard solution of known conductivity. The standard solutions can be purchased or prepared in the laboratory using a certified reference material.

Measurement Procedure

To measure the acidity or alkalinity of a solution with a conductivity meter, follow the steps below:

Step 1: Prepare the sample

The first step is to prepare the sample by ensuring that it is homogeneous and free from any impurities that may affect the conductivity. The sample should be at room temperature, and its pH should be noted for comparison with the conductivity measurement.

Step 2: Turn on the conductivity meter

Switch on the conductivity meter and allow it to warm up for a few minutes before use.

Step 3: Calibration

Calibrate the meter by adjusting it to a standard solution of known conductivity.

Step 4: Measurement

Dip the conductivity probe into the sample solution and wait for a stable reading. Take note of the reading and repeat the measurement three times to ensure consistency.

Step 5: Calculate the conductivity

The conductivity is calculated using the following formula:

Conductivity = (Measured value - Blank reading) x Calibration factor

Where the blank reading is the conductivity of the solvent used to prepare the sample, and the calibration factor is obtained during calibration.

Step 6: Determine the acidity or alkalinity

The acidity or alkalinity of the solution can be determined by comparing the conductivity with that of a standard solution of known acidity or alkalinity.

Applications of Conductivity Measurements

Conductivity measurements are widely used in various fields, including:

Monitoring of water quality in swimming pools, aquariums, and water treatment plants

Determination of ionic strength and pH in biological fluids, such as blood and urine

Measurement of soil salinity in agriculture

Quality control in the production of food, beverages, and pharmaceuticals

Analysis of electroplating solutions in the metal finishing industry


Conductivity measurements provide a reliable and accurate method of measuring the acidity or alkalinity of a solution. Calibration of the conductivity meter is essential to obtain accurate readings. The measurement procedure involves preparing the sample, turning on the meter, calibrating it, taking measurements, calculating the conductivity, and determining the acidity or alkalinity of the solution. Conductivity measurements have diverse applications in various fields.